Answer :
When baking soda (NaHCo3) reacts with water it produces a new substance such as carbonic acid which shows it is a chemical reaction because something new is produced. This reaction releases heat energy so we can say that it is an exothermic reaction.
Mixing baking soda and vinegar with each other will produce a new substance such as carbondioxide gas is produced which also show that it is a chemical reaction so we can conclude that both reaction represents chemical reaction.
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